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Therefore, DTCCSN2 values of isomers in SOA mixtures depend strongly in the mode of ionization in ESI. Furthermore, PSOA monomers and dimers display larger DTCCSN2 values (1-4%) than their particular LSOA alternatives due to more rigid frameworks. A cyclobutane ring occurs with useful groups pointing in opposite instructions in PSOA substances, in comparison with noncyclic flexible LSOA structures, developing more compact ions within the fuel stage. Lastly, we investigated the results