https://www.selleckchem.com/pr....oducts/otub2-in-1.ht
Although the construction and application of pillar[5]arene-based [1]rotaxanes have been extensively studied, the types of stoppers for them are limited. In this work, we designed and prepared three series of pillar[5]arene-based [1]rotaxanes (P5[1]Rs) with pentanedione derivatives, azobenzene derivatives, and salicylaldehyde derivatives as the stoppers, respectively. The obtained P5[1]Rs were fully characterized by NMR (1H, 13C, and 2D), mass spectra, and single-crystal X-ray analysis. We found that the synergic C-H···π, C-H···O int