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The activated PMS produced active species and followed the priority order of 1O2 SO4•- •OH for contaminants degradation, and the specific porous structure reduce the migration distance of active species for efficient catalysis. This study offers a deeper insight into the construction of regulable metal-oxo-bridge configurations for electron transfer towards PMS activation and contributes to an efficient strategy for wastewater remediation.A new adsorbent was prepared from municipal wastes (a mixture of Corn Stover, Paper Waste, a