https://www.selleckchem.com/pr....oducts/a-1155463.htm
The origin of the peak skewness that can be observed when applying the deconvolution method to isolate the diffusion process from the flow processes for peak parking experiments conducted under conditions of slow radial equilibration and strong trans-column velocity gradients was investigated. Numerical simulations were carried out for a variety of trans-column velocity profiles and a broad range of experimental conditions and system parameters were investigated. Results show that, under the aforementioned conditions, the traditionall