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In order to verify the proposed optimisation procedure, Zr-C coatings with different spatial distribution of carbon concentration were produced by the Reactive Magnetron Sputtering PVD (RMS PVD) method and their anti-wear properties were assessed by scratch test and ball-on-disc tribological test.A new lupane caffeoyl ester, lup-20(29)-ene 3β-caffeate-30-al (7), and a new oleanane-type triterpene, 3β-hydroxyolean-13(18)-en-12-one (17), were isolated from the aerial parts of Dobera glabra (Forssk), along with ten known triterpenes, inclu