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However, the impact of alkaline pretreatment on plant growth was not significant. Catalytic conversion of xylose and the hemicellulose fraction of waste biomass to furfural is important for the valorization of waste lignocellulose. Here, a clean and efficient catalytic system consisting of sulfonated carbon microspheres catalysts and γ-valerolactone was developed for the upgrading of xylose and waste lignocellulose to the furfural in one-pot. Sulfonated carbon microspheres (CCoS) with Brønsted and Lewis acid sites were prepared to yield fur