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This work identifies the different roles of Cu and Mn entities in toluene oxidation and provides the novel design strategy for toluene removal catalysts.Controllable recycling of End-of-life rechargeable nickel-metal hydride (Ni-MH) batteries and by-products of steelmaking to added-value functional nanostructures is desired but challenging. The present work introduces an innovative and high-yield microrecycling strategy to simultaneous synthesis of TM alloy (i.e., Ni-based superalloy) and RE oxide (REO) nanostructures from obsolete Ni-M