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Microwire crystal transistors of F4 BDOPV- and NDI-based polymers exhibit high electron mobilities of up to 5.58 and 2.56 cm2 V-1 s-1 , respectively, which are among the highest values in polymer crystals. This work presents a simple method to obtain polymer crystals and their precise microstructures, promoting a deep understanding of molecular packing and charge transport for conjugated polymers.Atherosclerosis is a chronic inflammatory disease arising due to an imbalance in lipid metabolism and maladaptive immune response driven by the