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The Mg-DIB also demonstrated a capacity retention of 77% at 5C, indicating its good rate performance. Moreover, the Mg-DIB exhibited a high discharge medium voltage of ∼1.83 V, thus enabling a high energy density of 174 W h kg-1 at 183 W kg-1 and 122 W h kg-1 at a high power density of 845 W kg-1, among the best of the reported magnesium-ion full batteries. Our work provides a new strategy to improve the performance of MIBs and other rechargeable batteries.Quaternary Cs2AgBiBr6 perovskites have been considered as a potential candidate to