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The DAE products are put together , along with a second linker, into a monolithic surface-mounted metal-organic framework (SURMOF) film. By Infrared (IR) and UV/Vis spectroscopy as well as by synchrotron X-ray diffraction, we show that the light-induced expansion modifications regarding the molecular DAE linkers multiply to yield mesoscopic and anisotropic length changes. Because of the special architecture and substrate-bondi