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Secondary organic aerosol formation in the atmospheric aqueous/particulate phase by photosensitized reactions is currently subject to uncertainties. To understand the impact of photosensitized reactions, photophysical and -chemical properties of photosensitizers, kinetic data, and reaction mechanisms of these processes are required. The photophysical properties of acetophenones, benzaldehydes, benzophenones, and naphthalenes were investigated in aqueous solution using laser flash excitation. Quantum yields of excited photosensitizers were