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Usually the presence of CO2/HCO3-/CO32- is often forgotten or considered only as a buffer or proton transfer catalyst. Outcomes obtained within the last few years mention that carbonates are fundamental individuals in a variety of oxidation procedures. This was first attributed to the synthesis of carbonate anion radicals via the reaction OH• + CO32- → CO3•- + OH-. Nonetheless, recent studies explain that the participation of carbonates in oxidation procedures is much more fu