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The prepared Si CNPs emitted green FL at 470 nm under the excitation at 350 nm. The FL signal of Si CNPs reveals a clear improvement into the presence of resorcinol (RC), because of the passivation of area trap states of Si CNPs via the binding of OH group of RC with the NH selection of Si CNPs, which permitted the forming of brand new radiative electron-hole recombination facilities. This was confirmed by some analytical experiments performed on zeta potential, FL life tim