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We report a novel synthesis of CsPbX 3 perovskite nanoplates (PNPLs) driven by SnX 4 (X = Cl, Br, I) salts and address the role played by these hard Lewis acids in directing the formation of PNPLs. Sn 4+ disturbs the acid-base equilibrium of the system, increasing the protonation rate of oleylamine and inducing an anisotropic growth of the nanocrystals. Sn 4+ cations influence the reaction dynamics due to its complexation with oleylamine molecules. By monitoring the photoluminescence excitation and photoluminescence (PL) spectra of the
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