https://www.selleckchem.com/pr....oducts/apocynin-acet
The photo-initiated defluorination of iridium hexafluoride (IrF6 ) was investigated in neon and argon matrices at 6 K, and their photoproducts are characterized by IR and UV-vis spectroscopies as well as quantum-chemical calculations. The primary photoproducts obtained after irradiation with λ=365 nm are iridium pentafluoride (IrF5 ) and iridium trifluoride (IrF3 ), while longer irradiation of the same matrix with λ=278 nm produced iridium tetrafluoride (IrF4 ) and iridium difluoride (IrF2 ) by Ir-F bond cleavage or F2 e