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After in situ selenylation, hydrothermally synthesized NiMoO4 was partially converted to NiSe2 and MoSe2, and the obtained NiMoO4/NiSe2/MoSe2 nanowires were used as a supercapacitor electrode material. The specific capacitance of the nanowired NiMoO4/NiSe2/MoSe2 was significantly higher than that of NiMoO4 at a current density of 1 A g-1 (955 vs. 489 F g-1). NiMoO4/NiSe2/MoSe2 also exhibited a high capacitance retention of 86.1% after 5000 cycles at 10 A g-1. The high supercapacitive performance of NiMoO4/NiSe2/MoSe2 can be ascribed to the