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The exchange trends of TCEP were characterized as volatilization in urban areas, but equilibrium in rural ones. TCEP showed the highest volatilization flux (1100 ng/m3/d), whereas TCIPP showed the highest deposition flux (-171 ng/m3/d). The significant diffusive fluxes of certain OPFRs, especially of those with suspected toxicities, suggested potential high exposure levels to these chemicals.Mining activity may cause heavy metal accumulation, which threatens human and animal health by their long-term persistence in the environment. This
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