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The chemometric analysis of GNA@Van@Bct@Van@AuNP enabled the obvious discrimination and detection of Gram-positive bacteria. For comparison, we also tested a smooth gold surface with the same procedure and a similar trend was observed with lower SERS activity.[Cu4(LRh)4]8- ([1]8-; LRh = Δ-[Rh(l-cysteinate)3]3-), with an empty tetrahedral CuI44+ core, was converted to [Cu4O(LRh)4]8- ([2]8-), with a mixed-valent CuI2CuII2O4+ core, in aqueous NaOH. A solid sample of the latter compound was converted back to [1]8- by heating under vacuum, wh
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