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This work ready a number of Al-containing silicates changed with organic ligands and SnO2 nanoparticles, that have been then utilized as catalyst in BVO and carboxylation. Characterizations revealed the morphology of the synthesized catalyst was altered from micron-sized thin sheets to smaller obstructs, after which to uniform nanoparticles (measurements of 50 nm) having the doped SnO2 nanoparticles with a size of 29 nm. All catalysts revealed high wager surface p