https://www.selleckchem.com/pr....oducts/Epinephrine-b
Reported here for the first time is the Ir-catalyzed γ-selective hydroboration of γ-substituted allylic amides under mild reaction conditions. A variety of functional groups could be compatible with reaction conditions, affording γ-branched amides in good yields with ≤97% γ-selectivity. We have also demonstrated that the obtained borylated products could be used in a series of C-O, C-F, C-Br, and C-C bond-forming reactions.A Brønsted base and Lewis acid cooperatively catalyzed 1,3-dipolar cycloaddition is rep
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