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Organic solid-state fluorescent crystals have received extensive attention owing to their remarkable and promising optoelectronic applications in many fields. Current methods to obtain organic fluorescent crystals usually involve two steps (1) solution phase organic synthesis and (2) crystallization of target fluorescent compounds. Direct transformation from nonfluorescent organic crystals to fluorescent organic crystals by postsynthetic modification (PSM) might be a potential alternative to the traditional methods. Although it is common

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