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Magnetically, CP6 reveals weak antiferromagnetic coupling amongst the GdIII ions. The solid-state luminescence properties of CP2, CP5 and CP6 were analyzed at background temperature and CP5 exhibits characteristic purple emission groups produced by the Eu3+ ion (CIE 0.53, 0.31), with luminescence quantum yields of 22%. Therefore, CP5 ought to be considered to be a potential optical material.Anion...π interactions are recently recognized weak supramolecular forces that are highly relevant to many types of electron-d

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