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QTAIM analysis furnished direct evidence for the existence of a shared and dative B-chalcogen and Co-chalcogen communications, correspondingly. In parallel into the development associated with the hydridoborate buildings, the responses additionally yielded tetracyclic species, [Cp*Co], 3 a and 3 b (3 a E=Se and 3 b E=S), wherein the bridgehead boron atoms tend to be enclosed by one chalcogen, one cobalt as well as 2
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