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5 ± 0.7) × 1011 cm3 mol-1 s-1 at 1 mbar to k(1-MA + O2) = (4.6 ± 0.9) × 1011 cm3 mol-1 s-1 at 3 mbar. While for 2-methylallyl + O2 no previous experimental data are available, the rate constants for 1-methylallyl are in agreement with previous work. A comparison is drawn for the trends of the high-pressure limiting rate constants and pressure dependences observed for the O2 recombination of allylic radicals with the corresponding reactions of alkyl radicals.The discovery of graphene (G) attracted considerable attention to the study of o
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