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Here, a biodegradable aliphatic polycarbonate smart elastomer, mPEG113-b-PMBC letter , was synthesized from aliphatic polycarbonate monomer with methoxy polyethylene glycol (mPEG113, 5.0 kDa) as initiator, which exhibited excellent mechanical properties, highly efficient self-repairing, and remarkable shape memory behavior. The polymers have outstanding self-healing ability for 150 min. Meanwhile, after 46.33 ± 1.18 s, the short-term shape of the obtained polymer was indeed restored. The outcomes of bi

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