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This study provides a versatile platform to enhance the nonlinear optical reaction of 2D materials and benefit the scalable generation of a coherent source of light and entangled photon pairs.Polyelectrolyte adhesives, either poly[2-(dimethylamino)ethyl methacrylate] or poly(methacrylic acid), functionalized with a surface-active calix[4]resorcinarene had been grafted onto silicon wafers. Adhesion researches on these grafted-to brushes utilizing polyelectroly