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6% to 104.2%. The results demonstrated that the Fe3O4@NHCS modified electrode had the characteristics of high sensitivity, good selectivity and reliability. The recent rapid advances in the synthesis, functionalization and application of nanomaterials have enabled scientists to develop metal nanoclusters (MNCs) stabilized with a variety of scaffolds/protecting ligands including thiols, polymers, proteins, dendrimers and nucleic acids. Considering the unique optical, electronic and physical properties of MNCs, they have been successfully