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A series of experiments for calcination and subsequent digestion to increase the grade of phosphate rock were performed. Fluorine and chlorine released by calcination and digestion were investigated. The forms of both elements were studied by sequential chemical extraction. The grades of raw and calcined phosphate rocks, and their phosphorus concentrates were confirmed according to the value of P2O5%. The results showed that fluorine and chlorine in phosphate rock mainly existed in carbonate-bound and residual forms. The grade of phosphate rock can

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