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For a more general case with δ α ≠ δ β , the regular sequence is broken down because of the contribution of the first excited vibronic state in each electronic state to L Z (t).ConspectusFor the past two decades, linear free energy scaling relationships and volcano plots have seen frequent use as computational tools that aid in understanding and predicting the catalytic behavior of heterogeneous and electrocatalysts. Based on Sabatier's principle, which states that a catalyst should bind a substrate neither too strongly nor too weakly,
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