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Three novel complexes, namely, penta-μ-acetato-bis(μ2-2-[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl-6-methoxyphenolato)-μ-formato-tetramanganese(II), [Mn4(C13H11ClN3O2)2(C2H3O2)5.168(CHO2)0.832], 1, hexa-μ2-acetato-bis(μ2-2-[2-(6-bromopyridin-2-yl)hydrazinylidene]methyl-6-methoxyphenolato)tetramanganese(II), [Mn4(C13H11BrN3O2)2(C2H3O2)6], 2, and catena-poly[[μ2-acetato-acetatoaqua(μ2-2-[2-(6-chloropyridin-2-yl)hydrazinylidene]methyl-6-methoxyphenolato)dimanganese(II)]-μ2-acetato], [Mn2(C13H11ClN3O2)(C2H3O2)3(H2O)]n, 3, have been syn
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