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Coal preparation by-products, such as coal gangue, are inferior fuels enriched with trace elements (TEs). Owing to the issues surrounding the disposal of coal preparation by-products and energy shortages, Chinese researchers have strongly advocated harvesting energy from by-products. However, the secondary environmental pollution caused by such by-products has been overlooked. In this study, we aimed to assess the contamination of soil and maize (Zea mays L.) near a coal gangue-fired power plant (CGPP) in Liupanshui City, Guizhou Province,