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nced solute-solvent interactions with vibrationally excited DF that induce a DF band redshift and hence a resonant overlap with solvent C-D modes, which facilitate the intermolecular energy transfer. Our work also suggests that potentials used to model energy relaxation need to capture the fine structure of solute-solvent interactions and not just the two-body part.A novel approach has been developed for the selective determination of cations or anions based on the application of Fourier transformed staircase sinusoidal voltammetry (