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Cellulose acetate (CA) is one of widely used polymers for chemical and medical applications due to its versatile physico-chemical functionalities. Although its recycle is available after a deacetylation process, the recycle process releases a huge amount of wastewater. Thus, this study investigated a direct disposal process of CA with its valorization to syngas (H2 and CO) through pyrolysis. To construct more environmentally benign process, CO2 was used as a co-feedstock with CA to simultaneously convert them into syngas. Pyrolysis of