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The second synthesis strategy involves the metalation of ionic liquids Cat[S-H] and Cat[Se-H] by protolytically highly active metal alkyls or amides Rn M. This rather general approach towards unknown chalcogenido metalates Catm [Rn-1 M(E)]m (E=S, Se) will be demonstrated in a research paper following this short review head-to-tail.Herein, we report the synthesis and characterization of homochiral macrocycles, in which molecular rigidity, combined with the presence of multiple functional groups, allow for the assembly of helical nanostruc