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Creating mesopores for the nano-ZSM-5 catalyst could further promote the diffusion of molecules in its micropores and improve the catalytic activity and stability. Inorganic alkali treatment of ZSM-5 usually removes internal silica for the existence of an aluminum distribution gradient and leads to a hollow structure. Herein, surface TPA+ adsorption-induced protective desilication and recrystallization successively occurred during hydrothermal treatment, and controllable mesopore fabrication was achieved. The evolution of mesopores and ac
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