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The sludge-based activated carbons (SACs) were prepared by sewage sludge and corn straw and modified by ferric nitrate. The H2S removal performance and the desulfurization mechanism of the modified SAC were studied. Results showed that breakthrough sulfur capacity and saturation sulfur capacity of the SAC prepared by recommended modification were 27.209 mg/g and 48.098 mg/g, which were as 4.68 times and 7.02 times larger as those before modification, respectively. Additionally, results showed that the desulfurization products of unmodifi