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This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.Delicate design of nanostructures for oxygen-evolution electrocatalysts is an important strategy for accelerating the reaction kinetics of water splitting. In this work, Ni-Fe layered-double-hydroxide (LDH) nanocages with tunable shells are synthesized via a facile one-pot self-templating method. The number of shells can be precisely controlled by regulating the template etching at the interface. Benefiting from the double-shelled structu