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The production of DFF from the real cellulosic wastewater was obtained with 118% yield based on 5-HMF conversion by HPMoV/meso-SiO2-NH2 (23) and oxygen, which was contributed to the one-pot conversion of sugar, furan and 5-HMF in the wastewater.Atmospheric coarse particulate matter (PM1 enriched with heavy metal(loid)s could pose potentially significant health risk to humans, while accurate health risk assessment calls for characterization of their bioaccessibility, besides the total contents. The health risk of major toxic heavy metal