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Compared with one dimensional gas chromatography providing a total peak capacity of 172 and 43 identified compounds, the analysis performance was much more improved with a capacity of 5840 and 235 identified compounds by using comprehensive heartcut multidimensional gas chromatography with the total analysis time of 15.3 h. By comparison within the same set of identified compounds, the one dimensional and multidimensional approaches provided the MS match scores of 769 ± 81 and 836 ± 88, respectively. In addition, the nonlinear relationsh
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