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To overcome this matter, a brand new narrow bandgap NFA TT-S-4F is reported by presenting 3,6-dimethoxylthieno[3,2-b]thiophene (TT) as π-spacers to get in touch electron-rich core with terminal groups, so as to upshift the LUMO degree and increase π-system. Whenever incorporating 10% TT-S-4F into binary system predicated on PTB7-ThIEICO-4F, the higher-LUMO-level of TT-S-4F, the enhanced charge mobilities, the reduced trap-assisted combo loss, and a finer nanofiber framework and in
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