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Further C-H⋯O inter-actions are observed and form either an opposing meth-oxy 'buckle' to join two mol-ecules together or a cyclic dimer.The structures are reported for five salts formed by reactions between N-(4-fluoro-phen-yl)piperazine and aromatic acids. In 4-(4-fluoro-phen-yl)piperazin-1-ium 2-fluoro-benzoate monohydrate, C10H14FN2+·C7H4FO2-·H2O, (I), the components are linked by a combination of N-H⋯O and O-H⋯O hydrogen bonds to form a chain of alternating R46(12) and R66(16) rings. The ionic components of 4-(4-fluoro-phen-yl)pipe
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