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The measured versus thermodynamically simulated SOx and HCl emissions were consistent. Neural network-based simultaneous optimizations of the non-linear dynamics of eight kinds of gases pointed to 50% and 14.4% reductions in the emissions and the pyrolytic temperature, respectively, with the 3% FeCl3, relative to the control.As a natural reduction mineral, pyrite (FeS2), was combined with biochar by simply ball milling technology to synthesize FeS2@biochar composite (BM-FeS2@BC) and applied for the removal of hexavalent chromium (Cr(VI))