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uinaldine/toluene with a similar Tg difference of its components.The manifold interactions of (E)- or (Z)-1,2-ditosylethene with a palladium( centre bearing picolyl-NHC carbene ligands have been studied thoroughly. (E)-1,2-Ditosylethene produces the expected and stable η2-olefin palladium complexes, whereas the coordination of the Z derivative alternatively promotes the isomerization of the olefin itself or an oxidative addition process depending on the steric bulkiness of carbene substituents and/or the adopted synthetic procedure. R
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