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Compounds 1 and 2 had been made of planar Co6 cluster SBUs or rare 1D manganese-hydroxyl chain SBUs, respectively. Both SBUs contain triangular MII3(OH) (M = Co and Mn) central units, which are connected by unusual syn,anti,syn,anti- and syn,syn,anti-coordinated formic acid or acetic acid. Both substances 1 and 2 have actually great thermal security, while compound 2 also exhibits an extraordinarily large dampness security. Magnetized scientific studies illus