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Glasses exhibit vibrational and thermal properties that are markedly different from those of crystals. While recent works have advanced our understanding of vibrational excitations in glasses in the harmonic approximation limit, efforts in understanding finite-temperature anharmonic processes have been limited. In crystals, phonon-phonon coupling provides an extremely efficient mechanism for anharmonic decay that is also important in glasses. By using extensive molecular dynamics simulation of model atomic systems, here we first descri