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Our results illustrated the lack of several high molecular weight carcinogenic PAHs in the DEP samples, unlike our measurements in major freeways of Los Angeles. Negligible levels of inorganic ions were observed in the sample and the DEP did not contain toxic secondary organic aerosols (SOAs) formed through synchronized reactions in the atmosphere. Lastly, the analysis of redox-active metals and trace elements demonstrated that the levels of many species including vehicle emission tracers (e.g., Ba, Ti, Mn, Fe) on Los Angeles roadways we