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In this work, we investigated the effect of Ag doping (2-20 at.%) on the phase formation of iron mononitride (FeN) thin films. Together with deposition of FeN using reactive dc magnetron sputtering, Ag was also co-sputtered at various doping levels between 2-20 at.%. We found that doping of Ag around 5 at.% is optimum to not only improve the thermal stability of FeN but also to reduce intrinsic defects that are invariably present in (even in epitaxial) FeN. Conversion electron Mössbauer spectroscopy and N K-edge x-ray near edge absorpt
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