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The Rice-Ramsperger-Kassel-Marcus (RRKM) theory was utilized to calculate reaction kinetics and product branching ratios. The RRKM results indicate that the formation of DNB- is exclusively important in the oxidation of DCA-, whereas the same type of reaction is a minor channel in the oxidation of DCBH-. In the latter case, H2 elimination becomes dominating. The RRKM modeling also indicates that the oxidation rate constant of DCBH- is higher than that of DCA- by an order of magnitude. This rationalizes the enhanced preignition performanc
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