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We report high photocatalytic hydrogen evolution from water-glycerol mixture under visible light illumination using sol-gel method synthesized zinc oxide (ZnO), Lutetium (Lu) modified ZnO and Lu modified ZnO/CNTs composite. X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), Brunauer-Emmett-Teller (BET), UV-Visible diffuse reflectance spectroscopy (UV-Vis DRS), photoluminescence (PL), X-ray photoelectron spectroscopy (XPS), photocurrent transient response and electrochemical impedance spectros