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More interestingly, enantiomeric excesses decrease and, in the case of SO3-, are even inverted in favor of the other enantiomer when the electron-donating groups are installed. These results highlight the importance of electrostatic effects, and polar effects more generally, in optimal organocatalyst design for stereoselective C-C bond-forming reactions.Lanthanide-transition metal complexes continue to be of interest, not only because of their synthetic challenge but also of their promising magnetic properties. Computational work examin
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